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31.
Flexible control of building blocks of photonic crystals enables achieving desirable band structures. Exploration of photonic band extrema has brought many fantastic features to design artificial optical materials, such as Brillouin‐zone‐corner extrema for valley photonic materials and zone‐center extremum for zero‐index metamaterials. However, two such kinds of extrema are always found independently in different photonic crystals. In this work, a kind of valley photonic crystals possessing both zone‐center and zone‐corner band extrema almost at the same frequency is proposed. Inspired by antennas theory, a three‐antenna array (TAA) source is devoted to individually manipulate each extremum. The correlation coefficient is given to determine the coupling efficiency between the TAA source and extrema eigenmodes. By using a source with a high correlation coefficient, these extrema bulk states are selectively excited consistent with their eigenfields. Furthermore, three control cases are shown that multiple extrema points are simultaneously excited, in order to confirm the validity of the correlation coefficient. Finally, a potential application of a beam‐steering device is proposed through selective excitation of ternary extrema. This work develops binary valley states into ternary mix states, rendering more degrees of freedom for on‐chip optical information transport, particularly for beam steering and mode division multiplexing. 相似文献
32.
Jiangyu Wu Meimei Feng Guansheng Han Benyu Yao Xiaoyan Ni 《Comptes Rendus Mecanique》2019,347(1):62-89
Investigating the dilatancy, acoustic emission and failure characteristics of fissured rock are significant to ensure their geotechnical stability. In this paper, the uniaxial and triaxial compression experiments with AE monitoring under different loading rates were carried out on fissured rock specimens with the same geometrical distribution of two pre-existing flaws. The dilatancy and AE activity of these specimens were discussed, and the effects of the confining pressure and loading rate on the mechanical parameters and failure characteristics were analyzed. The results show that the exponential strength criterion is more suitable than the Mohr–Coulomb strength criterion to characterize the strength characteristics of fissured rock. The crack evolution and failure characteristics of fissured rock specimens are more complicated than those of intact rock specimens. The failure characteristics of the fissured rock follow the tensile shear coalescence model, crack branching occurs with increasing the loading rate, and the multi-section coalescence model is verified with increasing the confining pressure. The phenomena of stress drop and yield platform usually occur after the dilatancy onset, the specimen does not fail instantaneously, and the propagation and coalescence of cracks cause a sharp increase in the AE signals, circumferential strain, and volumetric strain. 相似文献
33.
基于单粒子导心运动代码ORBIT,采用测试粒子模拟方法,研究了托卡马克等离子体内部不同径向位置处局域磁场扰动对高能量离子的损失的影响。研究表明,在局域磁扰动主要分布在某磁面附近、其环向具有类似纹波场形式下,可造成一些靠近等离子体中心区域的高能量离子损失,但对靠近等离子边界的离子损失影响相对不大。这些损失的高能量离子均为捕获离子,离子的投掷角越大就越容易损失。此外,造成高能量离子最大损失率的局域场径向位置与这些损失离子的初始径向位置通常存在一定的偏移,而且这个偏移与这些离子的能量密切相关。当局域场出现在某些位置时,能量较低的离子会有一定的损失,能量较高的离子反而不会损失。 相似文献
34.
Nathamgari S. S. P. Dong S. Hosseinian E. Lauhon L. J. Espinosa H. D. 《Experimental Mechanics》2019,59(3):349-359
Experimental Mechanics - Nanoelectromechanical (NEMS) systems fabricated using atomically thin materials have low mass and high stiffness and are thus ideal candidates for force and mass sensing... 相似文献
35.
36.
Wei Peng Jie Dong Han‐Bin Li Christine Chow Qiao‐Sheng Hu 《Journal of polymer science. Part A, Polymer chemistry》2019,57(14):1606-1611
Room temperature Suzuki cross‐coupling polymerization of aryl dibromides/diiodides with aryldiboronic acids/acid esters with t‐Bu3P‐coordinated 2‐phenylaniline‐based palladacycle complex, [2′‐(amino‐kN)[1,1′‐biphenyl]‐2‐yl‐kC]chloro(tri‐t‐butylphosphine)palladium, as a general precatalyst is described. Such room temperature Suzuki cross‐coupling polymerization is achieved by employing six equivalents or more of the base and affords polymers within an hour, with the yields and the molecular weights in general comparable to or higher than reported results that required higher reaction temperature and/or longer polymerization time. Our study provides a general catalyst system for the room temperature Suzuki cross‐coupling polymerization of aryl dibromides/diiodides with aryldiboronic acids/acid esters and paves the road for the investigation of employing other monodentate ligand‐coordinated palladacycle complexes including other electron‐rich monophosphine‐coordinated ones for room temperature cross‐coupling polymerizations. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1606–1611 相似文献
37.
Song Zi-Long Zhu Yun Liu Jing-Rui Guo Shu-Ke Gu Yu-Cheng Han Xinya Dong Hong-Qiang Sun Qi Zhang Wei-Hua Zhang Ming-Zhi 《Molecular diversity》2021,25(1):205-221
Molecular Diversity - Based on the strategy of diversity-oriented synthesis and the structures of natural product pimprinine and streptochlorin, two series of novel pimprinine derivatives... 相似文献
38.
Dongping Wang Jie Dong Wenjing Fan Prof. Dr. Xiang-Ai Yuan Prof. Dr. Jian Han Prof. Dr. Jin Xie 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(22):8508-8512
An unprecedented Mn(I)-catalyzed selective hydroarylation and hydroalkenylation of unsaturated amides with commercially available organic boronic acids is reported. Alkenyl boronic acids have been successfully employed for the first time in Mn(I)-catalyzed carbon–carbon bond formation. A wide array of β-alkenylated amide products can be obtained in moderate to good yields, which offers practical access to five- and six-membered lactams. This protocol has predictable regio- and chemoselectivity, excellent functional group compatibility and ease of operation in air, representing a significant step-forward towards manganese-catalyzed C−C coupling. 相似文献
39.
Yong-Jin Zhao Jian-Ping Ma Jianzhong Fan Yan Geng Yu-Bin Dong 《Acta Crystallographica. Section C, Structural Chemistry》2020,76(6):605-615
The tridentate organic ligand 4,4′,4′′‐(4,4,8,8,12,12‐hexamethyl‐8,12‐dihydro‐4H‐benzo[9,1]quinolizino[3,4,5,6,7‐defg]acridine‐2,6,10‐triyl)tribenzoic acid ( H3L ) has been synthesized (as the methanol 1.25‐solvate, C48H39NO6·1.25CH3OH). As a donor–acceptor motif molecule, H3L possess strong intramolecular charge transfer (ICT) fluorescence. Through hydrogen bonds, H3L molecules construct a two‐dimensional (2D) network, which pack together into three‐dimensional (3D) networks with an ABC stacking pattern in the crystalline state. Based on H3L and M(NO3)2 salts (M = Cd and Zn) under solvothermal conditions, two metal–organic frameworks (MOFs), namely, catena‐poly[[triaquacadmium(II)]‐μ‐10‐(4‐carboxyphenyl)‐4,4′‐(4,4,8,8,12,12‐hexamethyl‐8,12‐dihydro‐4H‐benzo[9,1]quinolizino[3,4,5,6,7‐defg]acridine‐2,6‐diyl)dibenzoato], [Cd(C48H37NO6)(H2O)3]n, I , and poly[[μ3‐4,4′,4′′‐(4,4,8,8,12,12‐hexamethyl‐8,12‐dihydro‐4H‐benzo[9,1]quinolizino[3,4,5,6,7‐defg]acridine‐2,6,10‐triyl)tribenzoato](μ3‐hydroxido)zinc(II)], [Zn2(C48H36NO6)(OH)]n, II , were synthesized. Single‐crystal analysis revealed that both MOFs adopt a 3D structure. In I , partly deprotonated HL 2? behaves as a bidentate ligand to link a CdII ion to form a one‐dimensional chain. In the solid state of I , the existence of weak interactions, such as O—H…O hydrogen bonds and π–π interactions, plays an essential role in aligning 2D nets and 3D networks with AB packing patterns for I . The deprotonated ligand L 3? in II is utilized as a tridentate building block to bind ZnII ions to construct 3D networks, where unusual Zn4O14 clusters act as connection nodes. As a donor–acceptor molecule, H3L exhibits fluorescence with a photoluminescence quantum yield (PLQY) of 70% in the solid state. In comparison, the PL of both MOFs is red‐shifted with even higher PLQYs of 79 and 85% for I and II , respectively. 相似文献
40.
针对未来空间天文学应用的超分辨率光谱成像仪器的需求,对低噪声柱面微通道板(MCP)的制备方法及其性能进行了研究. 提出了一种将光学抛光与热成型相结合的新的柱面MCP制备方法,利用不含放射性元素的低噪声MCP玻璃,制备出曲率半径为400mm、尺寸为30mm′46mm、长径比为80:1、通道直径12.5mm、通道间距15mm的柱面MCP,并将其与感应电荷楔条形阳极(WSA)组成光子计数探测器,对其暗计数率、分辨率进行了检测,暗计数率约为0.1counts/cm2×s. 相似文献